Gold-complexes catalyzed oxidative α-cyanation of tertiary amines.
نویسندگان
چکیده
Oxidative α-cyanation of tertiary amines is catalyzed by gold complexes with trimethylsilyl cyanide to afford the corresponding α-aminonitriles in the presence of tert-butyl hydroperoxide in good to excellent yields under acid-free conditions at room temperature.
منابع مشابه
Iron catalyzed oxidative cyanation of tertiary amines.
Iron(ii) and iron(iii) salts catalyze the oxidative alpha-cyanation of tertiary amines by trimethylsilyl cyanide in the presence of tert-butylhydroperoxide under acid-free conditions at room temperature.
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ورودعنوان ژورنال:
- Chemical communications
دوره 47 8 شماره
صفحات -
تاریخ انتشار 2011